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Comments 1 to 25 out of 121:

1. HumanityRules at 00:55 AM on 25 October, 2009
   The graph you show is not "The resultant change in outgoing radiation was as follows" as you state. What it is the data that has been manipulated to highlight the drops in radiance in the regions of the spectra that are absorbed by CO2 and CH4 (and other trace gases). The fact that no area of the graph goes above the 0 point (dotted line). The real observed data shows a large region of the spectra above the 0 line. You can see this in the original Harris 2001 paper (unfortunately subscription) or Fig 3 in the Chen paper (free access). What this says is there are other parts of the spectra which are letting more energy escape from the planet in 2006 than in 1970. if you take the CO2 part of the spectra in isolation this would suggest greater energy retention (global warming). If you highlighted just the positive areas (say spectra from 800-1000) you would conclude greater energy radiance (global cooling). If you took the whole of the spectra I'm not sure whether you'd conclude greater or less radiance in more recent years. Why don't people look at the whole of the spectra and what would be the explanation for greater radiance at other wavelengths? I accept that this analysis might be way of highlighting the CO2 'signature' in the spectra I don't see how you can conclude global warming without analysis of the whole wavelength spectra.
   Response: Harries 2001 does look at the full infrared spectrum except for wavelengths less than 700nm (which happens to be where a large portion of the CO2 absorption occurs). The observed changes in the spectrum from 1970 to 2006 are consistent with theoretical expectations. As the atmosphere warms, more infrared radiation is radiated to space. However, less infrared radiation escapes at CO2 wavelengths. The net effect is that less total radiation escapes out to space.
   
   This is independently confirmed by surface measurements which find the net result is more longwave radiation returning back to the Earth's surface (Philipona 2004, Evans 2006). It's also confirmed by ocean heat measurements which find the oceans have been accumulating heat since 1950 (Murphy 2009).
2. iskepticaluser at 13:33 PM on 20 November, 2009
   re comment 1 (HumanityRules), referring to apparent increases in radiation in the 800-1000 part of the spectrum in the Harries paper (the full version of which you can find through Google Scholar): on page two, 2nd column, that paper does indeed offer a potential explanation, viz. incompletely-cleared artifacts in the data (due to ice-cloud absorption). Considering the study is the first of its kind, its finding of reduced radiation precisely in the wavelengths associated with increased GHG concentrations remains remains highly suggestive, no?
3. Phil at 08:26 AM on 10 December, 2009
   Re #1 (Humanity Rules). My understanding is that Earth emissions are modeled as black body radiation. Given the earths temperature of ~298K that means the IR radiation emitted by the earth peaks at around 600cm-1 and tails off around 1500cm-1. There is this on-line model that allows you to play with the earths emissions. This is Climate science 101 so it may be hopelessly naive !
4. jabberwockey at 13:17 PM on 23 December, 2009
   Re #2 (Hugh) Considering the study is the first of its kind, its finding of reduced radiation precisely in the wavelengths associated with increased GHG concentrations remains remains highly suggestive, no? Suggestive that there is a slight increase heat absorbance of CO2 and MH4 - but only if you cherry pick the data. Any atmospheric gas that absorbs infrared is considered a GHG. If you look at the full data you will see that although there is some increase in the heat absorbance of CO2 and MH4, you are seeing more heat escape at wavelengths different from CO2 and MH4. When talking about the causation of global warming, what does that suggest about the "greenhouse effect"?
5. Riccardo at 19:15 PM on 23 December, 2009
   jabberwockey, it is nature that cherry picks wavelength as far as molecular absorption is concerned. On the contrary, thermal emission is broad band and it depends on temperature. Hence what you see in the full spectrum (the background) reflects the increase of surface temperature.
6. ConcernedCitizen at 00:52 AM on 6 February, 2010
   Some quesitons. 1) Graph one is derrived from the difference between two satelites launched 26 years apart. How are their sensors callibrated so that they would give the same readings on the same day? 2)Graph 2. Why is there no downward radiation for CFCs, HNO3 NO2 etc, as there is for CO2, when the first graph shows that their energy is being 'trapped' in the atmosphere? Additionally. from the picture showing solar light penetrating the atmosphere but terrestrial IR being trapped, what happens to the solar IR? The sun produces aproximately 400000 times as much IR at the frequency absorbed by CO2 as the earth. The atmosphere must therefore absorbs and re-radiate half of this back into space. Also given the far larger solar IR radiation the CO2 will be saturated. Additional IR from the earth is a tiny amount in comparison. Answers appreciated.
7. Riccardo at 01:47 AM on 6 February, 2010
   1) different satellites and/or instrumets are always calibrated against one another in a better way than just the reading on a single day. 2) the first graph is a difference between spectra taken in two different points in time; the second graph is just a point in time. The difference depenss on how much the relative contrbution changed over time. IR from the sun is indeed absorbed by CO2. When you calculate an energy balance in a layer of the atmosphere you take both the incoming and outgoing energy into account. The tiny amount of energy (one and something W/m2) taken up by increasing CO2 will not make the earth look like Venus but it's enough to increase the temperature by a couple of degrees, maybe three by the end of the century. That's unfortunately enough to produce a significant change in the biosphere. There is no saturation effect to help us. The lifetime of the CO2 excited state is short enough for the CO2 molecules to be ready to absorb more of the incoming photons.
8. ConcernedCitizen at 22:05 PM on 6 February, 2010
   @Ricardo. Point #2. That doesnt answer my question. Graph 1 shows energy being absorbed by all the gasses mentioned. Graph 2 shows enery be emitted by only some of them. Thats my point. How is it selective so that only some of the gasses emmit energy back o the surface which is what the second graph implies? Point #3. Energy ballance. So an increase in CO2 will absorb, and re-emit to space more IR from the sun as well as absorb and re-emit to earth more IR from the earth. Since the sun produces more IR than the earth how does the extra CO2 cause warming and not cooling? Point #4. Excited state duration. If the duration is less than 12 hours then all the energy absorbed by CO2 during the day will be lost at night. How does this generate net warming over a period of days-years? I am not being argumentative, I am geneuinely interested in the science behind GH gasses, it is just that logically there seem to be problems with the theory. I am glad you mentioned excited state durtation by the way because I could not find any information on this online and to me it is a critical factor in heat storage.
9. Riccardo at 01:40 AM on 7 February, 2010
   matt sykes, #2 fig. 1 is a difference spectrum between 1976 and 1990. It shows only the changes during this period of time. If you want to compare the spectrum in fig. 3 (an emission spectrum), you need an absorption spectrum from space looking down. You can play with this using calculated spectra #3 there's much more energy in the visible than IR coming from the sun. It is this that warms the earth, not the IR. As far as CO2 absorption is concerned, it's not true that the IR around the 700 cm-1 band is much more than what the earth emits at the same wavelength. Integrating it over all the IR is wrong. Then the earth emits in the IR and this emission happens to peak around a CO2 absorption band; part of it is trapped producing warming. This is the very basics of the greenhouse effect. #4 The lifetime of the excited state is of the order of nano- to -micro- seconds depending on temperature and pressure. The extra energy can be released in two ways, by re-emission of a photon or by thermalization by collision (warming) of the surrounding air molecules; the re-emitted part will be absorbed again by other CO2 molecules and the process repeats itself until the pressure is so low that the photons have a high probability to escape to empty space. This is the way it works, again the basics of the greenhouse effect. If you increase CO2 concentration you slow down the process. You clearly still get cooling at night but not all of the energy absorbed during the day. It is not going to happen even if you do not increase CO2. A good example is the moon which, having no atmosphere, have enormous temperature gradients across the day/night line. I would more easily believe in your genuine interest had you not said "that logically there seem to be problems with the theory". Given that dozens of really smart people have worked on this for decades you'd better ask yourself "am i missing something?".
10. ConcernedCitizen at 22:36 PM on 8 February, 2010
    @Ricardo. #2 OK, lets ignore thins since no one understands my quesiton. #3 According to this, http://en.wikipedia.org/wiki/File:Blackbody-lg.png, the sun emmits far more IR then the earth at the frequencies absorbbed by CO2. Surely all this IR saturates the CO2 in the atmopshere with energy, dwarfing the IR coning form the earth? #4 OK, so you say that the CO2 primarially rleases energy as a photon of light at the same frequency it absorbed it at, and that due toi the volume of CO2 it takes more than 12 hours for a photon on average to exit the atmosphere to space. Interesting you mention the moon, its daytime high is 105`c. Is it not the case that the reason the earth has a lower daytime high is because gasses in the atmosphere, including CO2, reduce the energy that strikes the surface? As for the throry of GH gas warming dont forget the poles are supposed to warm the most, but in fact only one of them is warming, so it seems the planet earth also has a problem with the theory. I am however prepared ot accept that I am in deed missing somehting, hence asking these quesitons.
11. ConcernedCitizen at 22:41 PM on 8 February, 2010
    Sorry, final quesuiton, you say CO2 can release energy as a photon or by direct warming of other molecules. Do you have any figures for the rough percentage of energy released by each meathod? Given CO2s absorbiton band is only 8% of the total IR spectrum 92% of any release as a black body would not be re-absorbed by another CO2 molecule and thus exit the atmosphere directly.
12. Riccardo at 23:26 PM on 8 February, 2010
    matt sykes, #3 the effect of CO2 is mainly on the band at about 700 cm^-1 or about 15 microns while the graph you show ends at 3 microns. Also, cosider that the absorption band is relatively narrow, it's really a tiny fraction. It'd be good if you calculate it yourself approximating the incoming radiation with the Plank formula, it will probably be more convincing than my words. #4 i did not say that "it takes more than 12 hours for a photon on average to exit the atmosphere to space.". Would it be so long you couldn't have significant day/night temperature variation; just the opposite is true. The warming of the poles depends on a lot of things, not least on atmospheric and oceanic circulation. Antarctica is "isolated" both by the Antarctic Circumpolar Current and by the strong westerly winds blowing in the Southern Oceans. No one expect the same warming as in the Arctic. I do not any rough figure on the ratio between collisional and radiative de-excitation. It quite complicated and it also depends on density and temperature. You can estimate the overall effect in the atmosphere from the ratio of the energy leaving the atmosphere over energy emitted by the surface. You last claim is definitely not true as can be easily seen in the absorption spectra of CO2 from space. Indeed, at the surface level the absorption lenth is pretty short, no way to escape directly to space.
13. ConcernedCitizen at 01:18 AM on 9 February, 2010
    #3 2, 4.3 and 15 microns in fact. The first of which is well inside the graph I linked to. This one shows even more clearly how cooler bodies release less IR than hotter ones. http://quantumfreak.com/wp-content/uploads/2008/09/black-body-radiation-curves.png Mind you, this isnt surprising. A piece of metal at 30 `C will be warmer to the hand than one at 20`C becaue it is producing more IR. As for calculating the IR of a particular frequency emitted by an object at a particular frequency, I dont know how to, perhaps you could direct me to the relevant formula althogh I think we have establisged that hotter bodies do produce more IR than cooler ones. #4. You said "You clearly still get cooling at night but not all of the energy absorbed during the day" I understodd this to mean that the energy absorbed during the day cane be entirely lost at night. If you meant something else then I appologise for misunderstanding you although my understanding seems logical still. #5 And there is clearly something else at play in the Arctic too since it is only as warm as it was in the 1930's. But, thats the complexity of climate! #6 But you cant fell from space what is happening to the energy absorbed by CO2. It is either re-emmitted at the same frequency and thus bounces around the atmosphere fomr mollecule to mollecule or it is emmitted as broad band radiation in which case all of it except the 8% absorbed by CO2 will end up released to space. So from a sensor looking down from space you will never see the CO2 absorbed energy, ie those banmds will be missing from the spectrum, regardless of the re-emmission mathod. However, if the re-emission is of broad band, ie black body radiation, than CO2 effectively converts narrow band to broad band radiation. This will increase the levels of non absorbed energy transmitted to space, which is what one of the other respondants above stated had occured in the later sattelite measurement.
14. ConcernedCitizen at 01:32 AM on 9 February, 2010
    @Ricardo. Just found an online Plank law calculator. For wavelenghts betweem 3.9 and 4.1 microns the sun produces 340,000 times as much energy as the earth. This is close to my orevious estimate of 400,000. So, what does all this SOlar IR energy do in the atmosphere in comparison to terrestrial IR? Is it blocked in the uper atmosphere, does it saturate the CO2? Is it absorbed and re-emmitted into space in tha same way as terrestrial IR is absorbed and re-emmitted to the surface? If so, and given that it is 400,000 times stronger the effect of CO2 is to actually reduce the IR at the surface, not increase it.
15. Riccardo at 05:10 AM on 9 February, 2010
    matt sykes, from about 2 to 8 microns IR from the sun is absorbed by water vapour, CO2 has no influence. Also, you still integrate over the whole IR, not just the CO2 bands. At 15 microns, instead, the atmosphere is transparent and the CO2 band is centered at the peak of the thermal emission, the overall effect is then larger. Go back to your Plank calculator but this time plugin in the right numbers for a meaningfull comparison. The visible is 0.4-0.8 microns, the CO2 absorbtion band is centered at 15 micron and with a width of 2 microns (14-16 microns, in reality it is much narrower than this). You end up with a ratio of the energy coming from the sun in the CO2 related absorption band and the visible of the order of 10^-4. Negligible. #6 In this very same post you can see absorption from CO2, you must be wrong. Indeed, the radiation abosrbed is re-emitted isotropically and part of it will be converted directly into heat in the atmosphere. At the top of the atmosphere you will see less radiation. I'd suggest to read how an idealized model works.
16. Riccardo at 05:31 AM on 9 February, 2010
    matt sykes, i forgot to add that in any case absorption of sunlight is included in the radiative transfer codes.
17. ConcernedCitizen at 03:53 AM on 16 February, 2010
    @Ricardo At 15 microns the sun produces 180 times as much energy as the earth. It is irrelevant how much energy the sun produces in the visible, it is the energy emmitted by the earth and absorbed by CO2 which is key. Your Siki link states: "Thus heat is easily let in, but is partially trapped by these gasses as it tries to leave. " This isnt true. Visible energy is let in, not heat. The heat of the sun is bloocked by the same GH gasses as block the heat going out. The difference is that thr sun produces far more heat than the earth. The net effect of GH ghasses is therefore to reduce the maximum temperaturs that would be otherwise acchieved, Consider the moon,. Its daytime temperature is 105`C. It gets this hot because it hasnt got an atmosphere.
18. Ned at 04:44 AM on 16 February, 2010
    The net effect of GH ghasses is therefore to reduce the maximum temperaturs that would be otherwise acchieved, Consider the moon,. Its daytime temperature is 105`C. It gets this hot because it hasnt got an atmosphere. Er, sorry, but no. The moon's daytime temperature may average +105C, but its nighttime temperature is around -150C. Thus, the mean temperature of the moon is around -20C. Now, the earth's albedo is higher than that of the moon, so if the atmosphere had no effect (or a cooling effect, as you claim) then the earth should be cooler than the moon. Fortunately for us, water vapor and CO2 in the atmosphere raise the earth's mean temperature via a phenomenon known as the greenhouse effect.
19. Stuart at 02:39 AM on 17 February, 2010
    Matt, I think I see where your mistaken understanding is coming from. I think you're calculating the spectral radiance from Planck's law (if not, please explain where you get your figure of 180). I get about 150 by my calculations, but that's close enough to demonstrate the problem. The thing is that spectral radiance has a rather complicated definition: energy per unit time per unit surface area per unit solid angle per unit frequency The surface area of the sun is different to the earth - it's about 12000 times greater. 150 times 12000 is actually about 1.8 million. Hence the sun produces about 1.8 million times as much energy at 15 microns. It's hotter and larger, so this shouldn't come as a great surprise. But consider the fact that the sun is radiating this energy out in all directions, and that the earth captures only a tiny proportion of that energy because of our small size. Even Jupiter only appears as a tiny dot in the sky without a telescope. We can work out exactly how much we capture by dividing the area of a circle the size of the earth by the surface area of a sphere at the radius of the earth's orbit: pi*(6400^2)/(4*pi*(150 million)^2) = 0.00000000046 Taking this, and the 1.8 million value found before into account, the earth would (in the absence of atmospheric absorption) radiate out about 1200 times as much energy at 15 microns as we receive from the sun. This isnt true. Visible energy is let in, not heat. The heat of the sun is bloocked by the same GH gasses as block the heat going out. Visible energy IS heat. The heat we get from the sun is mostly within the visible and the near infrared, because the sun is hot and has a blackbody curve centred in the visible. When we absorb it, we radiate it back into space according to a much cooler blackbody spectrum, deeper into the infrared. This is all fairly basic greenhouse theory, and I don't think you've quite grasped the science behind it.
20. Tom Dayton at 03:10 AM on 17 February, 2010
    Matt, the implication of what Stuart just explained in his next-to-last paragraph is that the energy coming from the Sun to the Earth is in the wrong wavelengths to be much absorbed by CO2, but the energy being emitted by the Earth is very much in the right wavelengths to be absorbed by CO2.
21. bit_pattern at 21:01 PM on 25 April, 2010
    Sorry, I meant Chen (2007) Here is the working link [Source]
    Response: Thanks for pointing that out - I've updated the link.
    [RH] Hotlinked paper in order to fix broken page formatting.
22. babelsguy at 05:08 AM on 18 May, 2010
    A related question about the basics of the greenhouse effect: I have been sent a "study" by a guy who claims that CO2 cannot be a greenhouse gas because any warming would cause an instant increase in outward radiation due to the increased temperature difference between the atmosphere and open space, which would immediately diminish the warming. I tried to discuss some sense into him, but in classic denier fashion, he remained stubborn that nobody so far could give him a "convincing" reason why his objection cannot be true. I tried the earth system's heat capacity, speed of propagation of temperature changes in a kilometer-thick atmosphere, dynamic equilibrium, I even quoted the paragraphs from "A History of Global Warming" at aip.org that say that the actual greenhouse effect is caused by a greenhouse gas concentration change at the tropopause, effectively shifting it into higher, cooler layers of the atmosphere, which radiate heat less effectively than warmer layers, which forces the whole of the temperature gradient in the atmosphere to do something like a parallel shift in order to achieve a high enough temperature at the tropopause to force enough radiation out into space to re-establish the equilibrium - all to no avail. What would you experts here tell him (assuming he might still be convinced)? Any reply very much appreciated! Cheers, babelsguy
23. Doug Bostrom at 07:12 AM on 18 May, 2010
    Babelsguy, your friend apparently has not so much a quibble with C02 as a GHG so much as he does with the concept of an atmosphere being able to trap heat. After all, what he believes applies to any GHG. How does he explain why Earth's climate is not the same as that of a planet with no atmosphere?
24. babelsguy at 17:50 PM on 18 May, 2010
    doug_bostrom, well, that is the interesting thing: He claims that his "study" would avoid all discussion of other issues but just show that CO2 (and the other GHGs) *cannot* be the culprit due to what he calls the energy balance question...
25. babelsguy at 07:04 AM on 20 May, 2010
    Well I have now worked out on my own why the bigger temperature difference between atmosphere and space does not cause an energy loss that lets global warming collapse again: There is no bigger temperature difference. Due to the absorption length of GHGs being much shorter than the height of the atmosphere, the only place that matters for outward radiation is the upmost layer of the atmosphere that radiates at all - minus the absorption length to any reasonably small non-absorbed residue. Because the GHG concentration change effectively shifts this outward radiating layer upward into colder heights, and the atmosphere below has an increasing temperature gradient towards the ground, the ground has to heat up "a lot" to let the boundary layer also heat up sufficiently *until is as warm as before*, so it can radiate enough to re-establish equilibrium! Q.E.D. So the guy's conclusion is wrong because his whole presupposition is wrong. Garbage in - garbage out.

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