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All IPCC definitions taken from Climate Change 2007: The Physical Science Basis. Working Group I Contribution to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change, Annex I, Glossary, pp. 941-954. Cambridge University Press.

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Comments 78801 to 78850:

  1. Gripping video of Arctic sea ice melting away before your eyes
    apriatelooksat50, the video is gripping, if you're interested in this kind of stuff. And it does simply show ice melting in the Beaufort Sea. Nothing wrong with that title, unless you're having a hard time thinking things through.
    Arctic sea ice melting in the summer is hardly news. I am not saying that annual Arctic sea ice extent has not declined.
    Indeed, Arctic sea ice has declined in summer. So fast even that it is very big news. Unless you don't want it to be news, of course.
  2. apiratelooksat50 at 23:29 PM on 24 July 2011
    Gripping video of Arctic sea ice melting away before your eyes
    DB @ 3 When one reads the title "Gripping video of Arctic sea ice melting away before your eyes", it is designed to play on emotions and imply something other than a natural cycle that occurs annually. Note: I am not saying that annual Arctic sea ice extent has not declined.
    Response:

    [DB] The title clearly and succinctly tells a story, the story of what the OP is about.  It is an example of "Not burying the lead".

    When one reads things into that beyond what is actually said, as you do, that is an example of Confirmation Bias/Cognitive Bias.  Your intransigence on adhering to a narrative (the "natural cycles" meme) being displayed here is a textbook example of what denialists do: rushing in to defend any perceived real or imaginary attack on anything that endangers their world of rose-coloured skies and green firetrucks.

    Well-done, sir.  As the Great One said, "It's 5-O'clock Somewhere".

  3. apiratelooksat50 at 23:24 PM on 24 July 2011
    Rising Oceans - Too Late to Turn the Tide?
    I disagree with a lot in this paper. Mainly, I don't agree with how they arrived at their figures. If we take empirical data maintained by the University of Colorado, and do some simple math, we get the following (I will even use the upper range). 89 years X 3.6 mm/year = 320.4 mm 320.4 mm = 12.6 inches That is hardly 3 feet.
  4. apiratelooksat50 at 23:00 PM on 24 July 2011
    Gripping video of Arctic sea ice melting away before your eyes
    This technology is really impressive. However, arctic sea ice melting in the summer is hardly news.
    Response:

    [DB] "arctic sea ice melting in the summer is hardly news"

    In your busy waving of straw you conveniently neglect that no one on this post has claimed that it was.

  5. OA not OK part 9: Henry the 8th I was (*)
    Bern, I hope you are not too much like Ken - take a minute to search out some previous comments by Ken (those that moderators did not delete). At the end a booklet with added bonus material, a centrefold widescreen version of figures 13 and 14, and discount coupons will be published here as a free download. Yes, as we said at the outset, this series is intended to allow readers to understand some of the more technical posts here and elsewhere. We saw phrases like "carbonate compensation depth" bandied around and we felt that few would have been able to actually explain or derive it.
  6. OA not OK part 9: Henry the 8th I was (*)
    I think perhaps Ken, like myself, is falling victim to the instant gratification that is so prevalent in modern society, so having to wait for the whole story to be revealed is almost excruciating... On the other hand, I quite like the pacing of the series of articles, and the bite-sized nature of each post. Are you planning to post an omnibus version when all the installments have been published, or let it stand as linked posts? Re the overall question - well, I think there have been enough studies published on the matter that it's pretty clear the oceans are a net sink of CO2 - and that this series is about explain just why that is so, rather than merely asserting it.
  7. Gripping video of Arctic sea ice melting away before your eyes
    For those who missed the link in the earlier post, there are some webcams located much closer to the North Pole, which can be seen here. Note that Webcam2 seems to have fallen over at a steep angle yesterday as it's supporting ice melts. This image from a couple of days ago shows plenty of meltwater & open seawater.
  8. Rising Oceans - Too Late to Turn the Tide?
    A foot rise of sea level along the Connecticut coast would prove very costly. Most of the states public parks would be in deep trouble. 1 foot rise would leave Rocky Neck state park http://www.ct.gov/dep/cwp/view.asp?a=2716&q=325256 and Hammonasset Beach State Park, http://www.ct.gov/dep/cwp/view.asp?a=2716&q=325210 Both In deep trouble. Both beaches are now suffering from severe erosion. The cities of New London & Groton (home of the US Sub Base) would face serious flooding during storms. With New London seeing permanent sections under water. New Haven, home to Yale would see flooding from winter storms and sewage problems. Bridgeport would see its deep water port extend into downtown!! With 2 feet of sea rise- possible by 2050. the costs for mitigating this are exponential. Yet we have many in the US Congress fighting over the chump change deficits we have now. Power in the hands of fools.
  9. China, From the Inside Out
    Agnostic @74, absolute levels of emissions are the only relevant factor at a global level, but at a national level, per capita emissions are crucial. The alternative thesis, that at a national level absolute emission levels are the only relevant factor leads directly to the absurd conclusion that in whatever final emissions mix is finally negotiated, the Vatican should be permitted the same absolute emissions level as Italy, and that Tuvalu (pop ten thousand) should be permitted the same absolute emissions level as China or the United States. Clearly that supposition is absurd, and the insistence on not using per capita emissions as the metric for international agreements and national targets is equally absurd - and can be shown to be so by simple reasoning about fairness. If, however, we commit to a limited per capita budget of CO2e emissions, then the equation becomes fairly simple: As you can see, on a per capita basis, with a target for only a 2 degree increase above industrial levels, China can increase its total emissions by almost 50%, so long as it peaks around 2020, and eliminates all emissions by 2030. In contrast, the US and Australia need to peak now, and eliminate all emissions by 2020. That rigorous target can be ameliorated by an international trade in emission rights. But if we are not in an a global agreement that provides for such trade, there is no excuse for not reducing emissions to zero in a decade (and that would involve negative economic growth). In the meantime China is clearly tracking very close to its appropriate target, even without trading. Whether they will continue to do so remains to be seen.
  10. Milankovitch Cycles
    "Rapid" being 10x slower at least than current warming rates.
  11. China, From the Inside Out
    The lifestyles of those AuStralians is pretty luxurious in comparison as well!
  12. China, From the Inside Out
    I enjoyed the insight into the Chinese way of life. The demonisation of the Chinese in the current Carbon Tax debate has been quite ludicrous when you compare the lifestyle described in the article with that of most Autralians. In relation to the one-up-manship over who is allowed to comment on climate issues based on their personal carbon footprint; while it is pretty obvious that air travel in its current form is not carbon nuetral there is very little that is. I have read in the Guardian that use of the Internet produces 300m tonnes of CO2/yr, so maybe once we have stopped flying anywhere we should also then turn off our computers for ever more as well. And as possibly I don't use my computer as much as Pierre does, do I then get to have more authority to propound my views? My point is that I have no idea what steps Rob or Pierre take in their day to day life to cut or offset their carbon use, but it is possible that Rob has reduced his to a point where a yearly flight to China to maintain family contact can be justified. Is this not what we all have to do? Reduce our carbon footprint, but we can make the choice over what is neccessary to our lives and work our reductions on those that are not.
  13. Rob Honeycutt at 15:17 PM on 24 July 2011
    China, From the Inside Out
    Agnostic... Definitely not trying to claim that all is well with China. There are clearly massive hurdles that face them. What encourages me is that they are actually doing things. They are taking things seriously while we in the west (yes, mostly the US) are trapped in political discord. My major point is that they are better positioning themselves to address the issue of carbon emissions. It more than ironical when I hear anyone complaining about China and what "they have to do" when we can't manage to do much anything at all. We (US again) are losing incredible opportunities to take action and move forward with every day that passes. China is moving forward every day.
  14. Gripping video of Arctic sea ice melting away before your eyes
    From which region of the Artic Ocean was this footage taken?
    Response:

    [DB] The buoy is approximately in the location of the crosshair placed on the map below:

    OBuoy2

  15. China, From the Inside Out
    An interesting article, though I would challenge its conclusion that “the West” will be playing catch-up to China before the end of the century – unless of course “the West” is an euphuism for the USA. It is true that in an effort to reduce visible pollution, the dirtiest emitters are either being closed or are being ordered to fit scrubbers to reduce their emissions. This of course refers to emission of particulates, not greenhouse gases which are steadily rising and are destined to do so for at least 50 years. Reducing aerosol emissions is commendable for popular health but it will result in an increase in the level of solar radiation reaching the earths surface which, in combination with growing CO2-e emissions, will result in escalating global warming. The primary problem facing China, India, in fact all major CO2-e emitters is clear and simple. It is to provide growing national energy needs while reducing the need to burn fossil fuels and by 2050, burning none. China has made a good but far from adequate start in this regard. Both fixed and mobile plant and equipment, including all forms of transport, need to transfer from oil-based fuels to electricity, a fact China is aware of as evidenced by its R&D into efficient electric vehicles, notably cars and trains. All very well you may say – but where is the increased level of electricity coming from, if not fossil fuels? Most of it will come from sunlight. The technology to achieve cost-efficient conversion of sunlight to electricity is not quite here yet but it is being developed in a number of countries albeit in a fragmented and inefficient way. When available, it will be willingly embraced by countries such as China which loath being increasingly dependent on the vagaries of supply and growing cost of imported fossil fuels. It is dangerously misleading to talk of how well China is doing with its low per capita CO2-e emissions. They are irrelevant as evidenced by the fact that Australian annual emissions, the highest per capita in the world, equate in total to a few days emissions by China. With regard to effect on global warming and climate change, the only relevant figure is the total emissions per country, not per capita. We delude ourselves if we “China has one of the lowest levels of CO2-e emissions per capita, so all is well with the world and China”. All is not well when China’s total emissions were over 7.7 billion tones in 2009. All is not well when China intends to increase those emissions every year for the next 40 years. Per capita, China does very well but in total it very clearly does not and it must do better – a lot better with power generation and industry which is largely unregulated and 40 years out of date when it comes to emissions.
  16. Eric the Red at 12:49 PM on 24 July 2011
    Milankovitch Cycles
    Rob, The timing correlates fine. It is the rapid warming that has me puzzled. One would think that since the changes in eccentricity occur slowly, that the temperature would follow at a similar pace. Yet, that does not appear to be the case. At least, according to the ice core data.
  17. Rob Honeycutt at 12:08 PM on 24 July 2011
    Milankovitch Cycles
    Camburn... Are you really trying to suggest that there is no relationship between the pace of glacial-interglaicals and Milankovitch cycles? Eric... Same question.
  18. 2nd law of thermodynamics contradicts greenhouse theory
    Must be a slow news day if everyone's willing to re-heat (ha ha) this thread. May I suggest a new article: "Heating up the Lexicon of Physics" or "HaIRNET: Heat and Infrared Radiation / Net Energy Transfer -- Could Be Important" or the new skeptical argument "GHE doesn't exist because you don't accept my definition of 'heat'."
  19. Milankovitch Cycles
    That is also one of the problems with the Milankovitch theory. That was my point, the correlation does not mean causeation. However, there may be a sudden force that we have as of yet not recognized. The force seems to initially drive global climate equally between hemispheres.
  20. OA not OK part 8: 170 to 1
    JeffT, the algebra gets a wee bit tricky but it is easy to define the fraction of each species only in terms of K1, K2 and [H3O+]. Try googling dissociation of a diprotic acid. If there is huge interest we may consider an extra post to go through the equations.
  21. 2nd law of thermodynamics contradicts greenhouse theory
    Thankyou mc. The link should be http://web.mit.edu/16.unified/www/SPRING/propulsion/notes/node119.html
  22. Christina McGraw at 10:29 AM on 24 July 2011
    OA not OK part 9: Henry the 8th I was (*)
    Ken Lambert @5. Skeptical Science - and other blogs - have plenty of good short posts on the impacts of OA. However, as we stated in the introduction to the series (and have mentioned several times since), the purpose of these posts is to give readers interested in the chemical and physical processes of OA the background information they need to understand the commentary on the web. We are certainly not introducing graduate-level concepts, but high school and 1st year university chemistry is helpful. Perhaps it was not clear that we would answer the How can we... question in the next post. The post has been modified to state this clearly.
  23. Eric the Red at 10:29 AM on 24 July 2011
    Milankovitch Cycles
    Whatever the effect of Milankovitch-driven cylces, on thing is clear from the temperature record - Earth slowly slips into an ice age over tens of thousands of years, followed by a sudden rise into a warm interglacial. Can Milankovitch theory explain this? This appears to be opposite to the bifurcation diagram.
  24. OA not OK part 9: Henry the 8th I was (*)
    Oh dear Ken. Haven't you been paying attention? The series will run to about 20 parts by the time we are done. Sit back and enjoy.
  25. 2nd law of thermodynamics contradicts greenhouse theory
    damorbel#1098: "If this 'ignorance of source temperature' on the part of photons is the basis of your science then I suggest you think again. " Please, not that again. You've already contradicted yourself on the topic of 'photon temperature' on this thread.
    Response:

    [DB] Perhaps a new rule: Damorbel's Law (ala Godwin's Law).

    When someone repeats/resurrects a point already refuted on the same thread by that selfsame poster, Damorbel's Law is invoked declaring the argument forfeit and all subsequent comments by that poster on that thread may be safely ignored.

    One may safely then consider it already invoked on this thread.

  26. LazyTeenager at 09:58 AM on 24 July 2011
    OA not OK part 9: Henry the 8th I was (*)
    Keith Hunter at 13:35 PM on 23 July, 2011 LT @1: they amount to the same thing. Henry's Law describes the equilibrium solubility of a gas for a given atmospheric concentration. --------- Are you sure? Henry's law only applies at low partial pressures. So at high partial pressure of CO2 what happens? Does the amount of CO2 dissolved in water reach a maximim limit in the same way that a dissolved solid reaches a limit?
    Moderator Response: Given the current atmospheric concentration of CO2, your line of questioning is not relevant to ocean acidification. Please stay on topic. Thank you for your help in this. Doug
  27. 2nd law of thermodynamics contradicts greenhouse theory
    With indulgence:
    "If in the interior of the same solid we imagine a plane M parallel to those which bound it, we see a certain quantity of heat flows across this plane during unit of time..."
    (My emphasis) Joseph Fourier, "The Analytical theory of Heat", 1878; p 105.
    "The concept of heat 'flowing' went out with the 'fluid' concept of heat i.e. caloric."
    Damorbel's theory of pedantary, 2011.
    "Did Fourier get it wrong?"
    "Title: Heat flow in the solidification of castings Author: Adams, Clyde M Advisor: Howard F. Taylor. Department: Massachusetts Institute of Technology. Dept. of Metallurgy Publisher: Massachusetts Institute of Technology Issue Date: 1953"
    "Title: Heat flow over the equatorial mid-Atlantic ridge. Author: Folinsbee, Robert Allin Advisor: Gene Simmons. Department: Massachusetts Institute of Technology. Dept. of Geology and Geophysics Publisher: Massachusetts Institute of Technology Issue Date: 1969"
    "Title: Heat flow in solidification of alloys. Author: Campagna, Alan John Advisor: Merton C. Flemings. Department: Massachusetts Institute of Technology. Dept. of Metallurgy and Materials Science Publisher: Massachusetts Institute of Technology Issue Date: 1970"
    Heat flow and material degradation during laser metal forming 1985 16.5 Steady Quasi-One-Dimensional Heat Flow in Non-Planar Geometry So not only is "heat flow" a concept used in various MIT dissertations throughout the 20th century, it is a concept used in MIT lectures on Thermodynamics in 2007.
    Moderator Response: [mc] Closed italics tag. Link to '16.5 Steady Quasi' missing.
  28. Milankovitch Cycles
    Well lets see. Milankovitch-driven change in TSI causes much bigger changes in albedo for NH compared to SH, that is clear. It also can cause a much bigger change in CO2 and CH4 because of vegetation change, methane hydrate location, and swamp sources of both gases. The change in GHG concentration particular creates a global forcing, not just a hemispheric one. The hypothesis is testable by doing the maths and seeing how the forcings work out. See Ch6 of AR4 for the numbers on change from LGM. The inter-hemispheric connection is only a "problem" if you wish to ignore GHG forcings. On the 100k problem with milankovitch, I do agree that we have too many theories and not enough data to test them. Not much of relevance to current climate change however.
  29. Milankovitch Cycles
    Rob: As good a guess as any. I have read so many theories on this, with none of them proveable. I know this article works on TSI basically because of the orbital changes. One thing this article does not mention, which I think at least bears thinking, is what effect does the magnetic field have? As we orbit with the Mil cycle, we are also doing a baycenter orbit. Then there is the stage 5 question when the cycle does not match the timing. I think the theory is interesting, but the lack of matching further back historically causes one to ponder the actual cause/effect question. The good thing is it causes one to think.
  30. Rob Honeycutt at 07:04 AM on 24 July 2011
    Milankovitch Cycles
    Camburn @ 14... How about ice albedo feedbacks? Melting ice in the Arctic is going to cause a more rapid albedo feedback that would Antarctic land ice. The total ice mass in Antarctica is many times what it is in the Arctic. Same reason we get Arctic amplification as a result of warming. Presumably the reverse would be true of cooling. This is just a quick guess on my part. Admittedly I'd have to do some research to justify the claim.
  31. Philippe Chantreau at 07:01 AM on 24 July 2011
    2nd law of thermodynamics contradicts greenhouse theory
    Damorbel is at it again, after demonstrating how willing he was to contradict himself for the sake of argument. "How do you suppose a remote sensing infrared thermometer works if it doesn't relate the photon energy to the temperature of the emitter?" The hot plate of my stove emits IR photons. So does the Sun. No "IR thermometer" can tell whether an IR photon comes from one or the other. We've been there already. Damorbel's total confusion with Wien's law was clearly exposed on that occasion. Now the confusion is back, this time with gravity. It never ends.
    Moderator Response: (DB) Everything has an ending, including one's patience in allowing PRATT to continue to be bandied about.
  32. Bob Lacatena at 06:53 AM on 24 July 2011
    2nd law of thermodynamics contradicts greenhouse theory
    1098, damorbel,
    All these arguments about 'back radiation' and the like appear to be based on this idea of heat as a fluid substance and the preictions do not fit the observations.
    This statement is not only wrong, but demonstrates a woefully poor understanding of the subject matter. You appear to be completely oblivious to radiative and molecular physics, and trapped in a 1960s mode. Please educate yourself.
    If this 'ignorance of source temperature' on the part of photons is the basis of your science then I suggest you think again. How do you suppose a remote sensing infrared thermometer works if it doesn't relate the photon energy to the temperature of the emitter?
    You clearly failed to comprehend anything I wrote. Please go back and reread it. At the same time, this statement also represents a complete lack of understanding of radiative physics. Again, go study.
    it applies not only at the microscopic (molecular) level but to the sub-molecular i.e. quantum level.
    No. Go study.
    But how can you have 1 (red) unit going from the atmosphere at 2deg. to the Earth at 5deg. How so? Did Fourier get it wrong?
    No, Fourier didn't, but you do. Go study.
    Any object, including volumes of air, moving in a gravitational field, changes its potential and kinetic energy according to...
    But we're not talking about moving parcels of air. We're talking about stationary air.
    ...but these movements must conform tho the conservation of momentum, potential and kinetic energy, don't you think?
    Okay, this makes it pretty clear that you're one of those people who thinks they know what they are talking about to the point that they are hopelessly lost. Hence, this is all a complete waste of time. Enjoy applying your personal version of physics to the world.
  33. Milankovitch Cycles
    From some final words of the article: "It seems that the Earth listens to the Northern Hemisphere when deciding to have an ice age. If the North and South are alternatively near and far from the Sun during summer, why has glaciation been globally synchronous?" This question was asked in the article, so I won't dig for references as the article states this as well. That is why I posed the question as there is really no known physical mechanism that would explain this phenomina which indiates we are missing something in the cause/effect relationship.
  34. 2nd law of thermodynamics contradicts greenhouse theory
    Re #1095 Sphaerica you write:- "In thermodynamics there is no such thing as "net heat flow". Yes, there is. Go study." The concept of heat 'flowing' went out with the 'fluid' concept of heat i.e. caloric. There have been many attempts to describe heat and the idea that heat is conserved was gradually replaced with the conservation of energy during the 2nd half of the 19th century. All these arguments about 'back radiation' and the like appear to be based on this idea of heat as a fluid substance and the preictions do not fit the observations. You write:- "If a molecule emits energy in the form of a photon, the receiving molecule does not and cannot know if the emitting molecule was warmer or cooler. The energy of a photon has the relationship E = hv, this is at the basis of quantum theory laid down by Max Planck and further developed by A Einstein, Werner Heisenberg etc., etc. in the early 20thC. This discussion has raised this point about 'photons not knowing the source temperature - I'm sure I have seen it before and it just isn't true! In this respect photons are no different to any other particles. If this 'ignorance of source temperature' on the part of photons is the basis of your science then I suggest you think again. How do you suppose a remote sensing infrared thermometer works if it doesn't relate the photon energy to the temperature of the emitter? Again you write:- "thermodynamics does not apply on an individual molecular level. It applies in aggregate (i.e. at the macroscopic level)." Since thermodynamics is base on the conservation of energy, not heat, it applies not only at the microscopic (molecular) level but to the sub-molecular i.e. quantum level. I suggest you are thinking of statistical mechanics which is indeed very useful for understanding ensembles of freely interacting particles. But statistical mechanics relies just as much on the conservation of energy and the conservation of momentum (both angular and linear) as does themodynamics and quantum mechanics. Further you write:- "I simplified the "temperatures" to 5 for the surface and 2 for the atmosphere, but they are clearly there. The surface temperature should be 4 (the amount coming from the sun) but it is 5. The extra "ray" is the red one, coming from the atmosphere." I am not sure of your meaning here. According to Fourier heat transfer is between two bodies according to the temperature difference you have in your diagram 2 units of heat going from the Earth at 5deg. to the atmosphere at 2 deg - quite possible. But how can you have 1 (red) unit going from the atmosphere at 2deg. to the Earth at 5deg. How so? Did Fourier get it wrong? You write:- "Thermodynamics does not allow gravity to violate (or suspend) the 2nd Law of Thermodynamics, any more than anything else might. [Did you even realize that when you argue that gravity maintains the temperature differential, it is in fact you who are violating the 2nd Law of Thermodynamics?]" What is missing from your argument is the conservation of energy, both potential and kinetic. Any object, including volumes of air, moving in a gravitational field, changes its potential and kinetic energy according to the strength of the gravitational field and the (vector) distance it moves; this is the argument that got Galileo into trouble. As for a volume of gas, it loses kinetic energy as it rises in a gravitational field, changing into potential energy therefore it cools, it is as simple as that. No need to talk about compression and expansion, gas is free to move as it likes in an atmosphere, but these movements must conform tho the conservation of momentum, potential and kinetic energy, don't you think?
  35. The Last Interglacial Part Two - Why was it so warm?
    Steve #15 - You've raised a very interesting question, which I can't answer. It would make a very good topic for a future post, which I'll look into.
  36. Milankovitch Cycles
    Dikran: I am working from memory at this point. One thing that always stuck to me was also called the Stage 5 problem. I will dig for the Northern/Southern thing. I thought this was common knowledge to anyone who has reserached the Milankovitch cycle.
    Moderator Response: [Dikran Marsupial] Fine, once you can find the data, we can discuss it, but until then it would be better not to distract from discussion of the existing issues.
  37. Milankovitch Cycles
    Dikran: I understand there are other forcings at work. But for the Milankovitch theory to hold up, the match between the hemmispheres should not be so.
    Moderator Response: [Dikran Marsupial] As I said, present some data that show on what timescale and to what degree they match. That way some meaningful discussion might result.
  38. The Last Interglacial - An Analogue for the Future?
    Andrew #30 - My statement in the post was intended to be ironic. I don't disagree with your explanation.
  39. Milankovitch Cycles
    There are still questions about exactly how changes in the earth's orbit affect the climate, and especially in why the climatic changes match in the Northern and Southern Hemispheres. Does anyone have an answer to this question? The match in climate changes on both hemispheres indicates that there are other forces in play as well.
    Moderator Response: [Dikran Marsupial] See CO2 is not the only driver of climate. Solar forcing (inlcuding Milankovic cycles) isn't the only forcing either. In addition, you would be better off stating on which timescales you think climatic changes match in the two hemispheres, preferably by refering to a specific dataset.
  40. 2nd law of thermodynamics contradicts greenhouse theory
    damorbel#1083: "distinguish between this compressive heating of the surface and the GH effect?. For me this is critical to the understanding of atmospheric physics and not often discussed." Perhaps an idea is 'not often discussed' because it is clear to most that it has little merit. You appeared as the champion of this idea as far back as comment #125 on this very thread, where the "death knell of the GHG hypothesis really is the effect of gravity on the atmosphere." Rumors of the 'death knell' of the 'GHG hypothesis' have been greatly exaggerated. This is not your personal soapbox; if you have nothing new to contribute, no one really enjoys reruns.
  41. DaneelOlivaw at 04:10 AM on 24 July 2011
    Why Wasn't The Hottest Decade Hotter?
    I've made a spanish version of the first graph for my blog. http://i.imgur.com/Vs9ls.jpg
  42. Why Wasn't The Hottest Decade Hotter?
    NOAA put that -0.1 W/m2 differently, by saying it amounts to 1/3 of the increased power of CO2 added since 2000, which has been offset by this stratospheric aerosol effect Solomon et al are suggesting. Last year NOAA said Solomon was looking at water vapor which she had also observed to be variable. She had calculated an effect that "caused surface temperatures to increase about 25 percent more slowly than they would have otherwise", since 2000. The paper. is the same one mentioned in previous comments. "Why Wasn't the Hottest Decade Hotter" is a good title for everything like this.
  43. JosHagelaars at 02:11 AM on 24 July 2011
    OA not OK part 8: 170 to 1
    @Keith Hunter Thanks for the free CO2Calc application. @Jeff T When you increase CO2 concentration in the atmosphere the equilibriums 7, 8, and 9 start shifting and the result is a lower pH, more HCO3(-) and less CO3(2-). In my opinion figure 3 shows this perfectly. Even though you increase the amount of carbon in the oceans by increasing the CO2, you get less CO3(2-). Less CO3(2-) means that equilibrium CaCO3 = Ca(2+) + CO3(2-) shifts to the right and the calcifying organisms won't like that. Look at the table in The Encyclopedia of Earth where you can see some estimates about these concentrations for different dates. And I think they mean by CT and AT : total dissolved CO2 and total alkalinity.
  44. Bob Lacatena at 01:41 AM on 24 July 2011
    2nd law of thermodynamics contradicts greenhouse theory
    1094, damorbel,
    ...so CO2 is always going to absorb heat from the warm atmosphere, both by absorbing radiation and molecular collision...
    This one statement is very, very, wrong, and a major source of confusion. First, the energy is being absorbed from the surface, not the surrounding atmosphere. Thus, the surface is warming the CO2, which is in turn warming the surrounding O2/N2 in the atmosphere (it's not the atmosphere warming the contained CO2). Basically, the CO2 absorbs the radiation from the surface (or from other layers of the atmosphere, but ignore that complexity for now). Before the CO2 is able to radiate that energy away again (usually) it collides with an O2 or N2 molecule and passes the energy on that way -- freeing it to absorb more radiation from other sources. Thus, the surface warms the CO2, and the CO2 warms the O2/N2. This behavior is more pronounced near the surface, where the air is denser and collisions are more frequent. As one rises in the atmosphere, and it becomes less dense, the chance of collision is reduced, and so, too, is the time between collisions as well as the chance of receiving energy through absorbing radiation (for the CO2 molecule). As a result, CO2 higher up is more likely to gain energy through a collision, and emit it through radiation. Thus, we have a gradually changing effect, where in the denser, lower atmosphere, CO2 acts to absorb radiation and transfer it to the (otherwise transparent to IR) O2 and N2 molecules. As one rises, the balance slowly changes, until one reaches the very upper troposphere and stratosphere, where the opposite is likely to occur, and CO2 actually acts to accentuate heat loss.
  45. Bob Lacatena at 01:34 AM on 24 July 2011
    2nd law of thermodynamics contradicts greenhouse theory
    damorbel, I'm not going to waste of lot of time here, because clearly many others have been down this road before, but here are a few salient points:
    In thermodynamics there is no such thing as "net heat flow".
    Yes, there is. Go study. To provide a simple example, thermodynamics does not apply on an individual molecular level. It applies in aggregate (i.e. at the macroscopic level). If a molecule emits energy in the form of a photon, the receiving molecule does not and cannot know if the emitting molecule was warmer or cooler. It does not and cannot discriminate based on the source of the photon. If that photon is of the correct frequency, then it is absorbed, no matter where it came from. To give another example, do you think that it is impossible to shine a flashlight into the sun? Of course not. The light from the flashlight (some of it) will reach the sun and be absorbed. Far more light/energy from the sun will of course reach and be absorbed by the flashlight. The net flow is from warmer (sun) to cooler (flashlight). but energy still has flowed from the flashlight to the sun.
    I can see nothing in your diagram that shows a warming effect on the surface, thare are no temperatures to be seen, it is not possible to argue for a warming effect without atleast two temperatures.
    Look again. I simplified the "temperatures" to 5 for the surface and 2 for the atmosphere, but they are clearly there. The surface temperature should be 4 (the amount coming from the sun) but it is 5. The extra "ray" is the red one, coming from the atmosphere. Take the time to actually study and understand the diagram before commenting further (although arguing without listening appears to be your modus operandi).
    As you decend through the atmosphere the pressure rises and the temperature rises.
    Wow, really? Except that the pressure is greater near the surface, but not increasing at any particular altitude. Again, no work is being done. The pressure at any altitude is constant. As such, gravity doesn't increase the temperature or artificially maintain a higher temperature. Yes, it maintains the pressure gradient, and a rising parcel of air will do work and cool. But barring that motion, and that actual expenditure of work, the atmosphere should still cool to restore the temperature differential (warm to cool, remember?). Thermodynamics does not allow gravity to violate (or suspend) the 2nd Law of Thermodynamics, any more than anything else might. [Did you even realize that when you argue that gravity maintains the temperature differential, it is in fact you who are violating the 2nd Law of Thermodynamics?] The misapplication of the laws of thermodynamics where they do not apply (i.e. a system that is not in thermodynamic equilibrium) is where people often go wrong here. That, and trying to over-simplistically apply basic theories and laws (PV=rRT, etc.) without considering all of the interactions and ramifications. In particular, the system is greatly complicated by quantum mechanics, and the fact that the substances involved may be transparent or opaque to various frequencies of radiation. The system is just far, far more complex than your simple model allows, and as such your simple model is incapable of adequately describing or bounding the system. I suggest you study the facts behind radiation (at the molecular level) in detail before proceeding further with your erroneous train of thought.
  46. 2nd law of thermodynamics contradicts greenhouse theory
    Re #1093 Tom Curtis you write:- "I did not mention energy transfer from the upper troposphere to the surface." If a temperature rise is to take place, from any cause, GHE or whatever, there must be an energy source. If it is CO2 in the upper atmosphere producing 'back radiation' that warms the surface, don't you agree that the GHG-caused-back-radiation must be some sort of energy source? You also write:- "In fact you could develop a model of the greenhouse effect in which all energy transfers within the atmosphere are convective" This unlikely, gas flow surely dominates but there is plenty of gas flow that is not convective; surely surface winds play an even more important role? To restrict your analysis to convection is going rather too far I suggest; how else, apart from ocean currents, is thermal energy going to get from the tropics to the poles? You also write:- "But introducing more CO2 to the atmosphere temporarily slows the rate at which energy leaves the atmosphere". Sorry but I cannot see how this can be the case. CO2 is a powerful radiator of thermal energy and on Earth CO2 is always warmer than deep space, even Fourier when writing about heat transfer recognised that is transferred in the direction of hot to cold, so CO2 is always going to absorb heat from the warm atmosphere, both by absorbing radiation and molecular collision so that it, together with the other GHGs, cools the planet very effectively by radiating to deep space. You argue :- "if you double the CO2 content, atmospheric radiation from lower in the atmosphere that formerly made it to space will be absorbed by the additional CO2 higher in the atmosphere." Indeed the change in height does change the radiation temperature by perhaps a few degrees but this only makes a small difference because the radiation to 2.7K (deep space) is for a temperature difference of about 200K (raised to the 4th power don't forget!); the few degrees change arising from height difference will have only a tiny effect. Also the higher effective radiation level means the radiating gas has a lower density so it cannot absorb all the radiation coming from below, some radiation will pass straight through without being reabsorbed by the upper levels because the gas density is dropping.
  47. 2nd law of thermodynamics contradicts greenhouse theory
    Damorbel @1085, I did not mention energy transfer from the upper troposphere to the surface. In fact you could develop a model of the greenhouse effect in which all energy transfers within the atmosphere are convective. In that purely convective model of heat transfer within the atmosphere, there is no energy transfer from the upper troposphere to the surface. Never-the-less there is a greenhouse effect, which differs minimally from the real greenhouse effect. In such a model, the Earth's surface is warmed entirely by the Sun. But introducing more CO2 to the atmosphere temporarily slows the rate at which energy leaves the atmosphere. That creates an imbalance between incoming and outgoing energy, which must be stored somewhere and is stored as additional heat. Once enough heat is stored, the energy balance is restored, and all energy lost (or gained) is matched by energy gained (or lost) meaning the stored heat remains constant. Consider a bath tub, with a tap which lets water in, and another tap on the drain which can control the rate at which water goes out. If you turn the inlet tap on full, and the outlet tap on full, the water level of the bath will be constant. If you then half close the outlet tap, the water level in the bath will rise, even though no water flows back up the outlet pipe into the bath. This is exactly analogous to how the greenhouse effect works, and your objection is equivalent to a know-it-all on the side lines saying you can't raise the water level by closing the outlet tap. Your further claim that increasing the CO2 content of the atmosphere will increase the radiation to space assumes that energy radiated at a lower level in the atmosphere is never absorbed by CO2 at a higher level in the atmosphere. If you do not make that transparently false assumption, it becomes obvious that if you double the CO2 content, atmospheric radiation from lower in the atmosphere that formerly made it to space will be absorbed by the additional CO2 higher in the atmosphere. It will then be reradiated, but because it is reradiated by a higher and hence colder gass, it will emit less energy to space. I note that Sphaerica's and Dikran's post above more than adequately cover your other errors. As they note, you have been fully rebutted on these points many times and at length in this thread. Consequently I know there is no point in debate with you. I have responded twice now so that any late comers to this thread have a clear statement of the nature of your errors, but will not respond further. As you obviously have nothing new to add, nor any desire to learn, may I suggest you take to heart the moderator's prior direction to you.
  48. 2nd law of thermodynamics contradicts greenhouse theory
    Re #1088 Sphaerica you write:- "While it is true that the measured pressure is higher closer to the ground... it stays that way. The pressure is not changing. To increase the temperature, you must compress the gas further. This clearly is not happening." As you decend through the atmosphere the pressure rises and the temperature rises. This is quite different from the bicycle pump, diesel engine etc. With the bicycle pump the ambient pressure remains the same so its temperature does not change, so the heat in the pump is tranferred into the ambient (thus the unchanging) temperature. The case of the atmosphere is quite different in that all the air at a given altitude heats up as you change that altitude, this means that the ambient temperature is changing at the same time, thus quite different from the bicycle pump example. It is a fact that, apart from wind blowing the air about a bit, the temperature gradient in the troposphere (not the absolute temperature!) is uniform over the entire globe because the force of gravity is, more or less, uniform also.
  49. Dikran Marsupial at 23:55 PM on 23 July 2011
    2nd law of thermodynamics contradicts greenhouse theory
    damorbel wrote: "I suggest that, from this argument, you would also accept that the 'net' transfer is from the warmer to the colder part of the atmosphere and thus it is the colder part that tends to be heated by the warmer surface." Yes, of course it is, and that is completely compatible with the commonly accepted physics of the GHE. BTW, your putting 'net' in quote strongly suggests you don't understand the reason it is there. It is a perfectly standard term, and it's meaning is key to your misunderstanding. "The logic of this is clear, CO2 in the atmosphere indeed radiates heat to deep space, cooling the planet down from the heating effect of the Sun" No, that does not follow logically. The CO2 in the amtosphere prevents heat from being radiated directly into space from the surface. Instead heat is only radiated to space from the upper trophosphere. The upper trophosphere is cooler than the surface, so there is less heat to radiate. Hence the more CO2, the higher in the trophosphere the radiating layer becomes, the colder this radiating layer is and the less heat that is radiated, not more. As for pressure gradients, I suggest we deal with the major flaw in your reasoning before getting on to more subtle points.
  50. 2nd law of thermodynamics contradicts greenhouse theory
    Re #1087 Sphaerica you write:- "In answer to all of your questions about net heat flow." I did not mention 'Net' heat flow on #1086. In thermodynamics there is no such thing as "net heat flow". Heat flow, Net or otherwise is a concept belonging to the caloric theory of heat, a theory not accepted since about 1845 following the work of James Joule on the conservation of energy. I suggest that, from this argument, you would also accept that the 'net' transfer is from the warmer to the colder part of the atmosphere and thus it is the colder part that tends to be heated by the warmer surface. The logic of this is clear, CO2 in the atmosphere indeed radiates heat to deep space, cooling the planet down from the heating effect of the Sun - more CO2 makes for a greater cooling effect by re-radiating the ('net) heat transferring from the surface by convection, evaporation (and condensation) of water, surface radiation, hurricanes etc., etc. PS I can see nothing in your diagram that shows a warming effect on the surface, thare are no temperatures to be seen, it is not possible to argue for a warming effect without atleast two temperatures.

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